多点多板多分型面注塑模具的简化设计

应用锁扣装置、组合拉杆结构，减少导柱数量，简化了多点多板多分型面注塑模具的设计。     

Synthesis and characterization of novel sulfonated poly(arylene ether ketone)s derived from 4,4'-sulfonyldiphenol

Summary Novel sulfonated poly(arylene ether ketone)s were prepared directly by aromatic nucleophilic polycondensation of 4,4'-sulfonyldiphenol with various ratios of 4,4'-difluorobenzophenone to 5,5'-carbonylbis(2-fluorobenzenesulfonate) in dimethyl sulfoxide. The resulting polyelectrolytes were characterized by IR, NMR, TGA and DSC. The 10% weight loss temperature of the products is higher than 510°C, and their glass transition temperature is above 260°C. The introduction of 4,4'-sulfonyldiphenol with powerful electron-withdrawing group, -SO₂₋, into the main chain of sulfonated poly(arylene ether ketone)s improves the thermal stability against desulfonation. The ion-exchange capacity and swelling of the polyelectrolyte membranes were measured, which are higher than 1.23meq/g and not higher than 20.9%, respectively. The membranes show very good perspectives in polymer electrolyte fuel cell (PEMFC) application. Received: 27 March 2002 / Revised version: 7 May 2002 / Accepted: 13 May 2002     

纳米材料在涂料中的应用

简述了纳米微粒的基本性质，介绍了几种典型的功能纳米材料在涂料中的应用．并探究其对涂料的改性原理．对应用中存在的问题进行了剖析。     

预测控制系统在PVC工业废水处理过程中的应用

介绍了预测控制系统具有适应复杂生产过程控制的原理、特点及其在PVC工业废水处理过程中的应用。指出,随着预测控制理论的不断发展和完善,其必将在工业生产过程中发挥越来越大的作用。     

硬脂酸柱撑类水滑石的制备及应用

采用离子交换法制备了硬脂酸柱撑类水滑石,并用红外光谱分析对其进行了表征.通过HAAKE流变仪、颜色测定仪研究了硬脂酸柱撑类水滑石与钙锌热稳定剂并用时的热稳定性,重点考察了水滑石的结构对PVC稳定性能的影响.结果表明硬脂酸柱撑类水滑石与钙皂/锌皂复配显著改善了PVC热老化过程中的初期着色性.     

Synthesis, characterization of bimetallic Sn-Zn-MCM41 and its catalytic performance in the hydroxylation of phenol

A series of Sn-Zn modified-MCM41 has been synthesized by direct hydrothermal method and characterized using ICP, XRD, TG/DTA, FT-IR, HRTEM and N_2-adsorption techniques. Catalytic performances of the obtained materials were evaluated in the hydroxylation of phenol with H₂O₂. Results indicated that all the samples exhibited typical hexagonal arrangement of mesoporous structure with high surface area and the heteroatoms were probably incorporated into the framework of MCM41. Catalytic tests revealed that the bimetallic incorporated materials were effective catalysts in the hydroxylation of phenol. The conversion of phenol could be reach to 56.8% for the catalysts with Sn: Zn: Si = 2.69: 4.57: 100 (molar ratio) under the optimized reaction conditions. Moreover, the materials containing Sn and Zn exhibited higher catalytic activity than monometallic Sn and Zn modified MCM41.     

气相法改性纳米二氧化硅表面

采用硅烷偶联剂A-151处理的纳米二氧化硅粒子，具有良好的疏水性，并且反应副产物没有腐蚀性，有利于保护设备和环境保护。分别用表面羟基数、亲油化度等性能来表征改性纳米二氧化硅的效果。红外光谱分析表明A-151确实已经和纳米二氧化硅表明的羟基发生了化学反应，通过透射电镜研究发现改性后纳米二氧化硅在乙醇中达到纳米级的分散。     

A new core–shell type fluorinated acrylic and siliconated polyurethane hybrid emulsion

A novel core–shell type fluorinated acrylic and siliconated polyurethane (FSiPUA) hybrid emulsion was prepared by seeded emulsion polymerization using siliconated polyurethane (SiPU) as a seed and forming the structure with SiPU as a shell and the copolymer of butyl acrylate (BA) with 2,2,2-trifluoroethylmethacrylate (TFEMA) as a core. SiPU was synthesized using isophorone diisocyanate (IPDI), polytetramethylene ether glycol (PTMG), polypropylene glycol (PPG), dihydroxybutyl-terminated polydimethylsiloxane (PDMS), dimethylol propionic acid (DMPA), 1,6-hexanediol (HDO) and triethylamine (TEA). The contents of siloxane and fluorine were determined according to the feed ratio. Fourier transform infrared spectroscopy (FTIR) was used to identify the chain structure of SiPU and FSiPUA. Investigation of transmission electron microscopy (TEM) confirmed the core–shell structure of FSiPUA emulsion and gave the particle size at about 50 nm. The measurement results of water contact angles and the solvent absorptions in water and n-octane for cured films showed that the water and the oil repellency for FSiPUA had been improved significantly with a suitable content of fluorine and siloxane.     

振动力场对聚丙烯/硅灰石复合材料性能的影响

采用三螺杆动态混炼挤出机通过熔融共混制备了聚丙烯(PP)/硅灰石复合材料,研究了振动工艺参数对材料力学性能及微观形态结构的影响。结果表明,PP/硅灰石复合材料的力学性能对振动参数的响应并不是单调增加,而是存在一个最佳的响应范围。在这一范围内,其综合力学性能得到极大提高。     

A_1-A_2-O-M工艺处理焦化废水的实验研究

采用厌氧-缺氧-好氧-复合(A1-A2-O-M)工艺处理焦化废水,考察了外加碳源和碱源对焦化废水COD和NH4+-N脱除效果的影响。试验结果表明:外加甲醇和碳酸氢钠对焦化废水的硝化和反硝化效果影响很小;不外加碳源和碱源时,焦化废水经处理后出水的COD和NH4+-N平均质量浓度分别为125.0mg/L和1.12mg/L,分别达到《污水综合排放标准》(GB8978-1996)中的二级标准和一级标准。